Reconstructions

PS
*ṣaw(ˀ)ar- - neck (SED I No. 258)
PS
*ṣyd/ṣwd - to go to and fro (Kogan 2015:540)
PS
*ŝˀm - to buy (LS 429)
PS
*ŝaˀn- - shoe (Kogan 2015: 215)
PS
*ŝaˁr- - hair (SED I No. 260)
PS
*ŝaˁr- - straw, grass (Kogan 2015: 40 n. 87, 199)
A derivation from PS *ŝaˁr- ‘hair,’ assumed as certain in Fronzaroli 1969: 12‒13 and elsewhere in Semitological studies, is difficult to prove, although a contamination with this widespread anatomical term cannot be excluded.
PS
*ŝVbVr- - buttocks, hind parts, small of the back (SED I No. 262)
PS
*ŝadaw- - open country, wild, uncultivated place (Fronzaroli 1968: 269‒270, 287; Kogan 2011: 190; Kogan 2015: 307)

reconstruction with *-w (rather than -y) seems to be assured by well-attested spellings with -u-/-w- in Sargonic (śa-dú-e, śa-dú-im) and Old Assyrian (ša-ad-wi-im, ša-du-im), v. Kienast 1994:278‒280 and CAD Š₁ 51 respectively

PS
*ŝahr- - moon (Kogan 2015:41, note 96)

Kogan 2015: “It is uncertain to what extent *ŝahr- was synonymous to *war(i)ḫ- in PS: could the former designate specifically the “new moon,” “crescent”?”

PS
*ŝaḥm- - fat (SED I No. 263; Kogan 2011: 215)

Cf. *ŝabḥ/*ŝVbḥ- "fat".